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Ei-ichi Negishi is confirmed dead at the age of 85.

Through the valley of death Ei-ichi Negishi has now passed. We are truly going to miss them but shall never forget.
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Ei-ichi Negishi
根岸英一
Nobel Prize 2010-Press Conference KVA-DSC 7398.jpg
Negishi in 2010
Born(1935-07-14)July 14, 1935
DiedJune 6, 2021(2021-06-06) (aged 85)
NationalityJapanese
CitizenshipJapan[1]
Alma materUniversity of Tokyo
University of Pennsylvania
Known forNegishi coupling
Spouse(s)Sumire Suzuki (m. 1959; died 2018)
Children2
AwardsSir Edward Frankland Prize Lectureship (2000)
Nobel Prize in Chemistry (2010)
Person of Cultural Merit (2010)
Order of Culture (2010)
Scientific career
FieldsChemistry
InstitutionsTeijin
Purdue University
Syracuse University
Hokkaido University
Doctoral advisorAllan R. Day
InfluencesHerbert Charles Brown
Ei-ichi Negishi (根岸 英一, Negishi Eiichi) (July 14, 1935 – June 6, 2021) was a Manchurian-born Japanese chemist who was best known for his discovery of the Negishi coupling. He spent most of his career at Purdue University in the United States, where he was the Herbert C. Brown Distinguished Professor and Director of the Negishi-Brown Institute. He was awarded the 2010 Nobel Prize in Chemistry "for palladium catalyzed cross couplings in organic synthesis" jointly with Richard F. Heck and Akira Suzuki.
Contents
1 Early life and education
2 Career
3 Recognition
3.1 Awards
3.2 Honors
4 Personal life and death
4.1 Disappearance
5 See also
6 References
7 External links
Early life and education
Negishi was born in Hsinking (today known as Changchun), the capital of Manchukuo, in July 1935, following the transfer of his father who worked at the South Manchuria Railway in 1936, he moved to Harbin, and lived eight years there. In 1943, when he was nine, the Negishi family moved to Incheon, and a year later to Kyongsong Prefecture (now Seoul), both in Japanese-occupied Korea. In November 1945, three months after World War II ended, they moved to Japan. Negishi graduated from the University of Tokyo in 1958 and did his internship at Teijin. He went on to study in the United States and obtained his PhD from the University of Pennsylvania in 1963, under the supervision of professor Allan R. Day.
Career
Peter Diamond, Dale T. Mortensen, Christopher A. Pissarides, Konstantin Novoselov, Andre Geim, Akira Suzuki, Ei-ichi Negishi, and Richard Heck, Nobel Prize Laureates 2010, at a press conference at the Royal Swedish Academy of Sciences in Stockholm.
After obtaining his PhD, Negishi decided to become an academic researcher. Although he was hoping to work at a Japanese university, he could not find a position. In 1966 he resigned from Teijin, and became a postdoctoral associate at Purdue University, working under future Nobel laureate Herbert C. Brown. From 1968-1972 he was an instructor at Purdue.
In 1972, he became an assistant professor at Syracuse University, where he was promoted to associate professor in 1979, before returning to Purdue University as a full professor in the same year.
He discovered Negishi coupling, a process which condenses organic zinc compounds and organic halides under a palladium or nickel catalyst to obtain a C-C bonded product. For this achievement, he was awarded the Nobel Prize in Chemistry in 2010. Negishi has also reported that organoaluminum compounds and organic zirconium compounds can be used for cross-coupling. He did not seek a patent for this coupling technology and explained his reasoning as follows: "If we did not obtain a patent, we thought that everyone could use our results easily."
In addition, Zr(C5H5)2 obtained by reducing zirconocene dichloride is also called Negishi reagent and is used for the synthesis of polysubstituted benzene.
Recognition
From left: Suzuki, Negishi, and Heck (2010)
In 2011, he was awarded an honorary doctor of science degree from the University of Pennsylvania.
Awards
1996 – A. R. Day Award (ACS Philadelphia Section award)
1997 – Chemical Society of Japan Award
1998 – Herbert N. McCoy Award
1998 – American Chemical Society Award for Organometallic Chemistry
1998-2000 – Alexander von Humboldt Senior Researcher Award
2003 – Sigma Xi Award, Purdue University
2007 – Yamada-Koga Prize
2007 – Gold Medal of Charles University, Prague, Czech Republic
2010 – Nobel Prize in Chemistry
2010 – ACS Award for Creative Work in Synthetic Organic Chemistry
2015 – Fray International Sustainability Award, SIPS 2015
Honors
1960-61 – Fulbright-Smith-Mund Fellowship
1962-63 – Harrison Fellowship at University of Pennsylvania
1987 – Guggenheim Fellowship, 1987
2000 – Sir Edward Frankland Prize Lectureship
2009 – Invited Lectureship, 4th Mitsui International Catalysis Symposium (MICS-4), Kisarazu, Japan
2010 – Order of Culture
2010 – Person of Cultural Merit
2011 – Sagamore of the Wabash
2011 – Order of the Griffin
2011 – Fellow, American Academy of Arts & Sciences
2012 – Honorary Fellowships of Royal Society of Chemistry (RSC)
2014 – Foreign Associate of the National Academy of Sciences
Personal life and death
Negishi married Sumire Suzuki in 1959 and together they had 2 children.
Disappearance
On the evening of March 12, 2018, both Negishi and his wife were reported missing by family members. Police determined that, based on a purchase made earlier in the day, the couple had left their home in West Lafayette, Indiana, and headed north. At about 5 a.m. the next day, officers in Ogle County, Illinois, received a call asking officers to check on the welfare of an elderly man who was walking on North Route 251, a rural road south of Rockford. When he was taken to hospital, local police found that police in Indiana were looking for the couple. A short time later, Suzuki's body was found on property of the Orchard Hills Landfill in Davis Junction, along with the couple's car.
According to a statement from the family, the couple was trying to get to the Rockford International Airport for a trip when their car became stuck in a ditch on a road near the landfall. Negishi went looking for help and was said to be suffering from an "acute state of confusion and shock." The Ogle County Sheriff’s Department said there was no suspicion of foul play in Suzuki's death, although her cause of death was not released. The family said X was near the end of her battle with Parkinson's disease at the time of her death.
See also
Japan portal
Biography portal
Chemistry portal
Negishi coupling
List of Japanese Nobel laureates
List of Nobel laureates affiliated with the University of Tokyo
List of Nobel laureates affiliated with the University of Pennsylvania
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